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Volume 6
Research & Reviews: Journal of Material Sciences
Advanced Materials 2018
September 19-21, 2018
September 19-21, 2018 Tokyo, Japan
22
nd
International Conference on
Advanced Materials and Nanotechnology
Wentao Peng, Res. Rev. J Mat. Sci. 2018, Volume 6
DOI: 10.4172/2321-6212-C4-023
Binary planet-satellite nanostructures using RAFT polymer
Wentao Peng
Georg-August-Universität Göttingen, Germany
The hierarchical self-assembly of distinct nanoelements into precisely ordered nanostructures requires efficient and flexible
fabrication strategies. We established the precise and simple methods to synthesize bimetallic (gold-planet–silver-satellite) and
metal-nonmetallic (silica-planet-gold-satellite) nanostructures using RAFT polymer as particle linker. For bimetallic systems,
we employed RAFT star polymer to connect planet AuNP (~13 nm) and AgNP (~8 nm). For silica-planet–gold-satellite
nanostructure, RAFT polymer is grown from SiO
2
NP (~35 nm) using surface-initiated RAFT polymerization technique.
The prepared nanoassemblies have well-defined structures in which a planet is encompassed by several satellites, thus
simultaneously incorporating the properties of both planet and satellite nanoparticles. The strength of this approach includes
the tunability of interparticle distance by tailoring the molecular weight of polymer molar mass. The precise arrangement
of distinct nanocomponents provides a template for 2D binary chemical patterning on nanoscale. We demonstrate the self-
assembly monolayer of planet-satellite nanostructures on substrate with subsequently plasma treatment removing polymer for
further chemical modification on nanoparticles. Our results highlight the general applicability of RAFT polymerization as a
nanosynthesis platform for fabricating hierarchical nanostructure.
Biography
Wentao Peng is currently a PhD Fellow in Macromolecular Chemistry at the Georg-August-Universität Göttingen, Germany. His research focuses on the
development of nanohybrid material based on novel nanocomponents and functional polymer for various applications.
wentaopengcustom@gmail.com