Synthesis and Spectral Kinetic Study of Fe (II) Demi-Macrocyclic Complex with N2O2 Ligand Ion
The demi-macrocyclic ligand complex of Fe(II) ions contain N and O as donor atoms was synthesized and by FTIR and UV-Vis. Spectroscopy. The magnetic susceptibility of the complex was measured and rate was determined spectrophotometrically to verify Βeer-Lambert law at required wavelength 235 nm. The effect of pH on reaction velocity was studied. The mechanism and rate law of complex formation in consistent with the activation parameters were evaluated.
Sameena Rasheed, Arvind Prasad Dwivedi*, Khan MU, Mir Bilal Parvaiz